A positron implanted into a solid thermalizes rapidly and then diffuses in the bulk until it annihilates with valence or core electrons. In a defect free lattice, this diffusion process lasts around 100 ps, during this period the positron typically covers a distance of 100 nm in a random walk. The positively charged atomic cores form a repulsive potential and hence, the positron is likely to be found between the atom positions.
This behavior changes, if open volume defects (like vacancies, dislocations or grain boundaries) can be found in the bulk. Due to the missing positive charge, a potential that attract positrons forms at these sites. Positrons approaching them during the diffusion process can be trapped in their potential well and annihilate there.
In positron annihilation studies (PAS), experimental techniques for the observation and investigation of positron trapping in defects are based on the detection of the annihilation radiation. Our group works on Doppler broadening spectroscopy (DBS). The motion of the electron leads to an Doppler shift in the annihilation radiation. Due to the smaller overlap of the positron with core electronic wavefunctions in vacancy like defects, the annihilation line is less broadened as in an ideal lattice. The broadening is characterized by the so called S-parameter, a high S-parameter corresponds to a narrow peak.
The coincident detection of the energies of both annihilation quanta (CDBS) reveals detailed information about the contribution of core electrons. These element specific information allow the identification of the chemical vicinity at the annihilation site.
In our CDB spectrometer, the NEPOMUC positron beam is used and hence, the implantation region can be shifted from the surface region up to several micrometer into the specimen. By CDBS, a depth dependent chemical analysis of the defect sturucture can be performed. In conventional DBS, a depth dependent analysis allows the investigation of positron diffusion and further increases the sensitivity range in the case of saturated trapping.